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Title: Kinetic study of the cyclohexadienyl radical. Part 4. - Combination and disproportionation with the allyl radical
Journal: Trans. Faraday Soc.
Volume: 65
Page(s): 2081 - 2088
Year: 1969
Reference type: Journal article
Squib: 1969JAM/KAM2081-2088
Reaction:
2,5-Cyclohexadiene-1-carboxylic acid 2-propenyl ester → CO2 + ·CH2CH=CH2 + 2,5-Cyclohexadien-1-yl
Reaction order:
1
Temperature:
403 - 473
K
Rate expression:
1.0x1015 [s-1] e-167121 [±16712 J/mole]/RT
Uncertainty:
10.0
Bath gas:
2,5-Cyclohexadiene-1-carboxylic acid 2-propenyl ester
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 403 | 2.18E-7 |
| 425 | 2.89E-6 |
| 450 | 3.99E-5 |
| 473 | 3.51E-4 |