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Accessibility information
Author(s):   James, D.G.L.; Kambanis, S.M.
Title:   Kinetic study of the cyclohexadienyl radical. Part 4. - Combination and disproportionation with the allyl radical
Journal:   Trans. Faraday Soc.
Volume:   65
Page(s):   2081 - 2088
Year:   1969
Reference type:   Journal article
Squib:   1969JAM/KAM2081-2088

Reaction:   2,5-Cyclohexadiene-1-carboxylic acid 2-propenyl ester → CO2 + ·CH2CH=CH2 + 2,5-Cyclohexadien-1-yl
Reaction order:   1
Temperature:   403 - 473 K
Rate expression:   1.0x1015 [s-1] e-167121 [±16712 J/mole]/RT
Uncertainty:   10.0
Bath gas:   2,5-Cyclohexadiene-1-carboxylic acid 2-propenyl ester
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
403 2.18E-7
425 2.89E-6
450 3.99E-5
473 3.51E-4