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Title: Homogeneous gas-phase thermolysis kinetics. An improved flow technique for direct study of rate processes in the gas phase
Journal: J. Phys. Chem.
Volume: 73
Page(s): 4056 - 4064
Year: 1969
Reference type: Journal article
Squib: 1969KWA/SAR4056-4064
Reaction:
CH3COOC2H5 → CH3C(O)OH + C2H4
Reaction order:
1
Temperature:
745 - 834
K
Rate expression:
1.87x1012 [s-1] e-195390 [±1954 J/mole]/RT
Uncertainty:
1.58
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 745 | 3.74E-2 |
| 750 | 4.61E-2 |
| 775 | 1.27E-1 |
| 800 | 3.27E-1 |
| 825 | 7.96E-1 |
| 834 | 1.08E0 |