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Title: Confirmation of the inertness of sulfur hexafluoride toward attack by CF3 and CH3 radicals
Journal: J. Phys. Chem.
Volume: 73
Page(s):
Year: 1969
Reference type: Journal article
Squib: 1969LEF/KAL1614
Reaction:
·CF3 + SF6 → CF4 + SF5
Reaction order:
2
Temperature:
303 - 638
K
Rate expression:
1.66x10-13 [cm3/molecule s] e-83976 [J/mole]/RT
Activation energy is a lower limit.
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 303 | 5.54E-28 |
| 325 | 5.29E-27 |
| 350 | 4.87E-26 |
| 375 | 3.34E-25 |
| 400 | 1.80E-24 |
| 425 | 7.93E-24 |
| 450 | 2.97E-23 |
| 475 | 9.68E-23 |
| 500 | 2.80E-22 |
| 525 | 7.33E-22 |
| 550 | 1.76E-21 |
| 575 | 3.91E-21 |
| 600 | 8.12E-21 |
| 625 | 1.59E-20 |
| 638 | 2.21E-20 |