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Accessibility information
Author(s):   Mitsch, R.A.; Rodgers, A.S.
Title:   Reactivities in olefin-difluorocarbene reactions
Journal:   Int. J. Chem. Kinet.
Volume:   1
Page(s):   439 - 450
Year:   1969
Reference type:   Journal article
Squib:   1969MIT/ROD439-450

Reaction:   1,3-Butadiene + ·CF2Cyclopropane,2-ethenyl-1,1-difluoro-
Reaction order:   2
Reference reaction:   (CH3)2C=C(CH3)2 + ·CF2 → Cyclopropane,1,1-difluoro-2,2,3,3-tetramethyl-
Reference reaction order:   2
Temperature:   309 - 364 K
Rate expression:   1.51x101±3.9 e-18708 [±748 J/mole]/RT
Bath gas:   1,3-Butadiene
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
309 1.04E-2
325 1.49E-2
350 2.44E-2
364 3.12E-2