
Kinetics Database Resources
Simple Reaction Search
Search Reaction Database
Search Bibliographic Database
Set Unit Preferences
Feedback
Rate Our Products and Services
Help
Other Databases
NIST Standard Reference Data Program
NIST Chemistry Web Book
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
More...
Administrative Links
NIST home page
MML home page
Chemical and Biochemical Reference Data Division
MML home page
Chemical and Biochemical Reference Data Division
|
Author(s):
Perettie, D.J.; Janz, G.J.
Title:
The rate of thermal decomposition of CF3CN
Journal:
J. Am. Chem. Soc.
Volume:
91
Page(s):
6590 - 6592
Year:
1969
Reference type:
Journal article
Squib:
1969PER/JAN6590-6592
Reaction:
C2F6 + NCCN → CF3CN + CF3CN
Reaction order:
2
Temperature:
957 - 1080
K
Rate expression:
5.25x10-9 [cm3/molecule s] e-314287 [J/mole]/RT
Bath gas:
CF3CN
Category: Experiment
Data type:
Derived from detailed balance/reverse rate
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
| 957 |
3.68E-26 |
| 975 |
7.63E-26 |
| 1000 |
2.01E-25 |
| 1025 |
5.06E-25 |
| 1050 |
1.22E-24 |
| 1075 |
2.81E-24 |
| 1080 |
3.31E-24 |
|