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Title: Syntheses and reactions of chloroderivatives of C2 hydrocarbons. I. Thermal dehydrochlorination of 1,1,2-trichloroethane
Journal: Russ. J. Phys. Chem. (Engl. Transl.)
Volume: 43
Page(s): 356 - 359
Year: 1969
Reference type: Journal article
Squib: 1969PIM/TRE356-359
Reaction:
CHCl2CH2Cl → CH2=CCl2 + HCl
Reaction order:
1
Temperature:
723 - 798
K
Rate expression:
1.31x1016 [s-1] e-271052 [±16296 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 723 | 3.43E-4 |
| 725 | 3.88E-4 |
| 750 | 1.74E-3 |
| 775 | 7.06E-3 |
| 798 | 2.37E-2 |