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Title: Some hydrogen atom abstraction reactions of CF2H and CFH2 radicals, and the C-H bond dissociation energy in CF2H2
Journal: Int. J. Chem. Kinet.
Volume: 1
Page(s): 509 - 525
Year: 1969
Reference type: Journal article
Squib: 1969PRI/PER509-525
Reaction:
n-C4H10 + ·CH2F → Other Products + CH3F
Reaction order:
2
Reference reaction:
·CH2F + ·CH2F → CH2FCH2F
Temperature:
450 - 559
K
Rate expression:
2.19x10-12 [cm3/molecule s] e-48972 [J/mole]/RT
Bath gas:
(CH2F)2CO
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 450 | 4.53E-18 |
| 475 | 9.03E-18 |
| 500 | 1.68E-17 |
| 525 | 2.94E-17 |
| 550 | 4.90E-17 |
| 559 | 5.82E-17 |