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Title: Kinetics and mechanism of thermal decomposition of 1,1,2,2-tetrachlorethane and pentachlorethane in the gas phase
Journal: Kinet. Catal.
Volume: 10
Page(s): 28 - 35
Year: 1969
Reference type: Journal article
Squib: 1969SHV/LEB28-35
Reaction:
CHCl2CCl3 → C2Cl4 + HCl
Reaction order:
1
Temperature:
697 - 721
K
Rate expression:
3.98x1011 [s-1] e-167121 [J/mole]/RT
Bath gas:
CHCl2CCl3
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 697 | 1.19E-1 |
| 700 | 1.35E-1 |
| 721 | 3.11E-1 |