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Accessibility information
Author(s):   Atkinson, R.; Thrush, B.A.
Title:   Photochemical studies of unimolecular processes
Journal:   Proc. R. Soc. London A
Volume:   316
Page(s):   131 - 141
Year:   1970
Reference type:   Journal article
Squib:   1970ATK/THR131-141

Reaction:   1,3,5-CycloheptatrieneToluene
Reaction order:   1
Temperature:   636 - 653 K
Rate expression:   3.5x1013 [s-1] e-213682 [J/mole]/RT
Bath gas:   1,3,5-Cycloheptatriene
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
636 9.88E-5
650 2.36E-4
653 2.83E-4