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Author(s):
Baldwin, R.R.; Walker, R.W.; Webster, S.J.
Title:
The carbon monoxide-sensitized decomposition of hydrogen peroxide
Journal:
Combust. Flame
Volume:
15
Page(s):
167 - 172
Year:
1970
Reference type:
Journal article
Squib:
1970BAL/WAL167-172
Reaction:
CO + ·OH → CO2 + H·
Reaction order:
2
Reference reaction:
H2 + ·OH → H2O + H·
Temperature:
298 - 2000
K
Rate expression:
4.15x10-13 [cm3/molecule s] e-1879 [J/mole]/RT
Bath gas:
H2O2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Other (direct)
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
| 298 |
1.94E-13 |
| 300 |
1.95E-13 |
| 400 |
2.36E-13 |
| 500 |
2.64E-13 |
| 600 |
2.85E-13 |
| 700 |
3.01E-13 |
| 800 |
3.13E-13 |
| 900 |
3.23E-13 |
| 1000 |
3.31E-13 |
| 1100 |
3.38E-13 |
| 1200 |
3.44E-13 |
| 1300 |
3.49E-13 |
| 1400 |
3.53E-13 |
| 1500 |
3.57E-13 |
| 1600 |
3.60E-13 |
| 1700 |
3.63E-13 |
| 1800 |
3.66E-13 |
| 1900 |
3.69E-13 |
| 2000 |
3.71E-13 |
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