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Title: Free-radical substitution in aliphatic compounds. Part 20.-Gas-phase photolytic chlorination of butane and 2-methylpropane by t-butyl hypochlorite
Journal: Trans. Faraday Soc.
Volume: 66
Page(s):
Year: 1970
Reference type: Journal article
Squib: 1970BRO/NEC2029
Reaction:
n-C4H10 + (CH3)3CO → tert-C4H9OH + n-C4H9
Reaction order:
2
Reference reaction:
(CH3)3CO → (CH3)2CO + ·CH3
Reference reaction order:
2
Temperature:
283 - 343
K
Pressure: 0.27 bar
Rate expression:
2.7x10-5±1.1x10-5 e38080 [±1522 J/mole]/RT
Bath gas:
tert-C4H9OCl
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 283 | 2.88E2 |
| 300 | 1.15E2 |
| 325 | 3.56E1 |
| 343 | 1.70E1 |