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Title: Free-radical substitution in aliphatic compounds. Part 20.-Gas-phase photolytic chlorination of butane and 2-methylpropane by t-butyl hypochlorite
Journal: Trans. Faraday Soc.
Volume: 66
Page(s):
Year: 1970
Reference type: Journal article
Squib: 1970BRO/NEC2029
Reaction:
(CH3)3CO → (CH3)2CO + ·CH3
Reaction order:
2
Temperature:
283 - 343
K
Pressure: 0.27 bar
Rate expression:
4.17x10-9 [cm3/molecule s] e-65269 [J/mole]/RT
Bath gas:
tert-C4H9OCl
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 283 | 3.74E-21 |
| 300 | 1.80E-20 |
| 325 | 1.35E-19 |
| 343 | 4.79E-19 |