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Title: Comparative rate single-pulse shock tube studies on the thermal decomposition of cyclohexene, 2,2,3-trimethylbutane, isopropyl bromide, and ethylcyclobutane
Journal: Int. J. Chem. Kinet.
Volume: 2
Page(s):
Year: 1970
Reference type: Journal article
Squib: 1970TSA311
Reaction:
Cyclohexene → C2H4 + 1,3-Butadiene
Reaction order:
1
Reference reaction:
Cyclobutane, ethyl- → C2H4 + 1-C4H8
Temperature:
950 - 1100
K
Pressure: 2.03 - 6.08 bar
Rate expression:
2.0x1015 [s-1] e-280198 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 950 | 7.85E-1 |
| 975 | 1.95E0 |
| 1000 | 4.63E0 |
| 1025 | 1.05E1 |
| 1050 | 2.30E1 |
| 1075 | 4.86E1 |
| 1100 | 9.90E1 |