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Title: The Use of the H2 + O2 Reaction in Determining the Velocity Constants of Elementary Reactions in Hydrocarbon Oxidation
Journal: Symp. Int. Combust. Proc.
Volume: 13
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971BAK/BAL291
Reaction:
n-C4H10 + H· → H2 + sec-C4H9
Reaction order:
2
Temperature:
298 - 753
K
Rate expression:
3.65x10-10 [cm3/molecule s] e-35337 [J/mole]/RT
Uncertainty:
1.38
Category: Experiment
Data type:
Derived from detailed balance/reverse rate
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 2.34E-16 |
| 300 | 2.57E-16 |
| 325 | 7.65E-16 |
| 350 | 1.95E-15 |
| 375 | 4.37E-15 |
| 400 | 8.88E-15 |
| 425 | 1.66E-14 |
| 450 | 2.89E-14 |
| 475 | 4.75E-14 |
| 500 | 7.43E-14 |
| 525 | 1.11E-13 |
| 550 | 1.61E-13 |
| 575 | 2.25E-13 |
| 600 | 3.06E-13 |
| 625 | 4.07E-13 |
| 650 | 5.29E-13 |
| 675 | 6.73E-13 |
| 700 | 8.43E-13 |
| 725 | 1.04E-12 |
| 750 | 1.26E-12 |
| 753 | 1.29E-12 |