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Title: Shock tybe pyrolyses. Part II. Thermal decompositions of isopropyl, n-butyl, isobutyl and t-butyl fluorides
Journal: J. Chem. Soc. A
Page(s): 248 - 252
Year: 1971
Reference type: Journal article
Squib: 1971CAD/DAY248-252
Reaction:
Butane, 1-fluoro- → 1-C4H8 + HF
Reaction order:
1
Reference reaction:
n-C3H7Cl → CH3CH=CH2 + HCl
Temperature:
1260 - 1660
K
Pressure: 1.08 - 1.10 bar
Rate expression:
1.91x1013 [s-1] e-237794 [±9478 J/mole]/RT
Uncertainty:
5.0
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1260 | 2.65E3 |
| 1275 | 3.46E3 |
| 1300 | 5.33E3 |
| 1325 | 8.07E3 |
| 1350 | 1.20E4 |
| 1375 | 1.77E4 |
| 1400 | 2.56E4 |
| 1425 | 3.67E4 |
| 1450 | 5.19E4 |
| 1475 | 7.25E4 |
| 1500 | 1.00E5 |
| 1525 | 1.37E5 |
| 1550 | 1.85E5 |
| 1575 | 2.48E5 |
| 1600 | 3.30E5 |
| 1625 | 4.34E5 |
| 1650 | 5.67E5 |
| 1660 | 6.29E5 |