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Title: The thermal decompositions of carbamates. I. Ethyl n-methyl-N-phenylcarbamate
Journal: Aust. J. Chem.
Volume: 24
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971DAL/ZIO2541
Reaction:
Carbamic acid, methylphenyl-, ethyl ester → C2H4 + N-Methylbenzenamine + CO2
Reaction order:
1
Temperature:
602 - 653
K
Pressure: 1.95E-3 - 0.26 bar
Rate expression:
2.75x1012 [s-1] e-189570 [J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 602 | 9.79E-5 |
| 625 | 3.95E-4 |
| 650 | 1.61E-3 |
| 653 | 1.89E-3 |