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Accessibility information
Author(s):   Flowers, M.C.; Parker, R.M.
Title:   Kinetics of the Thermal Gas Phase Reactions of cis- and trans-2,3-Epoxybutane
Journal:   J. Chem. Soc. B
Year:   1971
Reference type:   Journal article
Squib:   1971FLO/PAR1980

Reaction:   cis-2,3-DimethyloxiraneC2H5COCH3
Reaction order:   1
Temperature:   668 - 740 K
Pressure:  1.60E-2 - 3.73E-2 bar
Rate expression:   3.98x1013 [s-1] e-235300 [±2353 J/mole]/RT
Uncertainty:   1.62
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
668 1.59E-5
675 2.46E-5
700 1.10E-4
725 4.44E-4
740 9.80E-4