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Accessibility information
Author(s):   Hautecloque, S.
Title:   Reactions des radicaux CCl3 avec C2H6 et C2D6. Effet isotopique
Journal:   C.R. Acad. Sc. Paris
Volume:   272
Year:   1971
Reference type:   Journal article
Squib:   1971HAU2094

Reaction:   C2H6 + ·CCl3CHCl3 + ·C2H5
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   521 - 578 K
Rate expression:   3.47x10-10 [cm3/molecule s] e-75745 [J/mole]/RT
Bath gas:   CCl3Br
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
521 8.84E-18
525 1.01E-17
550 2.22E-17
575 4.57E-17
578 4.96E-17