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Title: Reactions des radicaux CCl3 avec C2H6 et C2D6. Effet isotopique
Journal: C.R. Acad. Sc. Paris
Volume: 272
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971HAU2094
Reaction:
C2H6 + ·CCl3 → CHCl3 + ·C2H5
Reaction order:
2
Reference reaction:
·CCl3 + ·CCl3 → CCl3CCl3
Temperature:
521 - 578
K
Rate expression:
3.47x10-10 [cm3/molecule s] e-75745 [J/mole]/RT
Bath gas:
CCl3Br
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 521 | 8.84E-18 |
| 525 | 1.01E-17 |
| 550 | 2.22E-17 |
| 575 | 4.57E-17 |
| 578 | 4.96E-17 |