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Author(s):   Strausz, O.P.; O'Callaghan, W.B.; Lown, E.M.; Gunning, H.E.
Title:   Reactions of Sulfur Atoms. XII. Arrhenius Parameters for the Addition to Olefins and Acetylenes
Journal:   J. Am. Chem. Soc.
Volume:   93
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971STR/OCA559

Reaction:   1,3-Butadiene + SThiirane, ethenyl-
Reaction order:   2
Reference reaction:   C2H4 + SThiirane
Reference reaction order:   2
Temperature:   298 - 450 K
Pressure:  0.27 bar
Rate expression:   2.4 e8564 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 7.61E1
300 7.44E1
325 5.71E1
350 4.55E1
375 3.74E1
400 3.15E1
425 2.71E1
450 2.37E1