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Accessibility information
Author(s):   Tschuikow-Roux, E.; Millward, G.E.; Quiring, W.J.
Title:   Kinetics of the shock wave pyrolysis of pentafluoroethane
Journal:   J. Phys. Chem.
Volume:   75
Page(s):   3493 - 3498
Year:   1971
Reference type:   Journal article
Squib:   1971TSC/MIL3493-3498

Reaction:   C2F5HC2F4 + HF
Reaction order:   1
Temperature:   1180 - 1470 K
Pressure:  3.87 - 5.33 bar
Rate expression:   3.98x1013 [s-1] e-299321 [±8980 J/mole]/RT
Uncertainty:   2.51
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1180 2.24E0
1200 3.72E0
1225 6.87E0
1250 1.24E1
1275 2.17E1
1300 3.74E1
1325 6.31E1
1350 1.04E2
1375 1.70E2
1400 2.71E2
1425 4.25E2
1450 6.57E2
1470 9.21E2