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Accessibility information
Author(s):   Tschuikow-Roux, E.; Millward, G.E.; Quiring, W.J.
Title:   Kinetics of the shock wave pyrolysis of pentafluoroethane
Journal:   J. Phys. Chem.
Volume:   75
Page(s):   3493 - 3498
Year:   1971
Reference type:   Journal article
Squib:   1971TSC/MIL3493-3498

Reaction:   C2F5H·CF3 + ·CHF2
Reaction order:   1
Temperature:   1180 - 1470 K
Pressure:  3.87 - 5.33 bar
Rate expression:   3.98x1016 [s-1] e-386623 [±23197 J/mole]/RT
Uncertainty:   5.0
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1180 3.06E-1
1200 5.90E-1
1225 1.30E0
1250 2.78E0
1275 5.77E0
1300 1.16E1
1325 2.28E1
1350 4.37E1
1375 8.18E1
1400 1.50E2
1425 2.68E2
1450 4.70E2
1470 7.28E2