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Title: Some hydrogen abstraction reactions of the trichloromethyl radical
Journal: Int. J. Chem. Kinet.
Volume: 3
Page(s):
Year: 1971
Reference type: Journal article
Squib: 1971WAM/KUN283
Reaction:
Cyclooctane + ·CCl3 → CHCl3 + Cyclooctyl radical
Reaction order:
2
Reference reaction:
·CCl3 + ·CCl3 → CCl3CCl3
Temperature:
372 - 449
K
Pressure: 0.14 - 0.24 bar
Rate expression:
2.14x10-12 [cm3/molecule s] e-40159 [±8314472 J/mole]/RT
Uncertainty:
1.95
Bath gas:
Cyclooctane
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 372 | 4.92E-18 |
| 375 | 5.46E-18 |
| 400 | 1.22E-17 |
| 425 | 2.48E-17 |
| 449 | 4.56E-17 |