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Accessibility information
Author(s):   Yates, B.L.; Ramirez, A.; Velasquez, O.
Title:   The thermal decomposition of β-hydroxy esters
Journal:   J. Org. Chem.
Volume:   36
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971YAT/RAM3579

Reaction:   (CH3)2C(OH)CH2C(O)OCH3(CH3)2CO + CH3C(O)OCH3
Reaction order:   1
Temperature:   563 - 593 K
Rate expression:   2.19x1011 [s-1] e-163795 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
563 1.39E-4
575 2.89E-4
593 8.18E-4