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Title: Thermal Unimolecular Decomposition of 1-Ethylcyclohexa-1,4-diene, 1,2-Dimethylcyclohexa-1,4-diene and Bicyclo[4.3.0]nona-1(6),3-diene
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 68
Page(s):
Year: 1972
Reference type: Journal article
Squib: 1972COC/FRE1287
Reaction:
1,4-Cyclohexadiene, 1-ethyl- → Ethylbenzene + H2
Reaction order:
1
Temperature:
589 - 652
K
Pressure: 1.33E-2 bar
Rate expression:
1.32x1013 [s-1] e-192064 [±1921 J/mole]/RT
Uncertainty:
1.23
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 589 | 1.22E-4 |
| 600 | 2.51E-4 |
| 625 | 1.17E-3 |
| 650 | 4.86E-3 |
| 652 | 5.42E-3 |