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Title: Thermolytic Reactions of Esters. Part VI. A Study on the Steric and Polar Nature of the β-Elimination Mechanism
Journal: Rec. Trav. Chim. Pays/Bas
Volume: 91
Page(s):
Year: 1972
Reference type: Journal article
Squib: 1972TIN/KOO3
Reaction:
1,2-Cyclohexanol diacetate, cis- → CH3C(O)OH + 2-Cyclohexen-1-ol acetate
Reaction order:
1
Temperature:
648 - 733
K
Rate expression:
5.01x1012 [s-1] e-201210 [±6028 J/mole]/RT
Uncertainty:
3.1600001
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 648 | 3.03E-4 |
| 650 | 3.39E-4 |
| 675 | 1.35E-3 |
| 700 | 4.85E-3 |
| 725 | 1.60E-2 |
| 733 | 2.30E-2 |