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Accessibility information
Author(s):   Alfassi, Z.B.; Golden, D.M.; Benson, S.W.
Title:   The Very Low-Pressure Dehydrogenation of cis-2-Butene. The Activation Energy for 1,4-H2 Elimination
Journal:   Int. J. Chem. Kinet.
Volume:   5
Page(s):  
Year:   1973
Reference type:   Journal article
Squib:   1973ALF/GOL991

Reaction:   (Z)-2-C4H81,3-Butadiene + H2
Reaction order:   1
Temperature:   1100 - 1300 K
Rate expression:   1.0x1013 [s-1] e-271883 [±8156 J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 1.23E0
1125 2.38E0
1150 4.48E0
1175 8.20E0
1200 1.46E1
1225 2.55E1
1250 4.35E1
1275 7.27E1
1300 1.19E2