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Title: Reaction kinetics of ground state fluorine, F(2P), atoms. I. Measurement of fluorine atom concentrations and the rates of reactions F + CHF3 and F + Cl2 using mass spectrometry
Journal: Can. J. Chem.
Volume: 51
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973CLY/MCK3596
Reaction:
CHCl3 + ·F → ·CCl3 + HF
Reaction order:
2
Temperature:
298
K
Pressure: 2.00E-3 bar
Rate expression:
5.3x10-12 [±1.33x10-12 cm3/molecule s]
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
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