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Accessibility information
Author(s):   Clyne, M.A.A.; Walker, R.F.
Title:   Absolute rate constants for elementary reactions in the chlorination of CH4, CD4, CH3Cl, CH2Cl2, CHCl3, CDCl3 and CBrCl3
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   69
Page(s):   1547 - 1567
Year:   1973
Reference type:   Journal article
Squib:   1973CLY/WAL1547-1567

Reaction:   CHCl3 + Cl·CCl3 + HCl
Reaction order:   2
Reference reaction:   CCl3D + Cl·CCl3 + DCl
Reference reaction order:   2
Temperature:   298 - 1010 K
Pressure:  7.73E-4 - 1.48E-3 bar
Rate expression:   9.68x10-1 e3201 [±160 J/mole]/RT
Uncertainty:   1.1
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 3.52E0
300 3.49E0
350 2.91E0
400 2.53E0
450 2.28E0
500 2.09E0
550 1.95E0
600 1.84E0
650 1.75E0
700 1.68E0
750 1.62E0
800 1.57E0
850 1.52E0
900 1.48E0
950 1.45E0
1000 1.42E0
1010 1.42E0