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Title: The thermal decompositions of carbamates. III. Ethyl N,N-dimethylcarbamate and the effect of N-substitution upon the β-elimination
Journal: Aust. J. Chem.
Volume: 26
Page(s): 1259 - 1262
Year: 1973
Reference type: Journal article
Squib: 1973DAL/HEW1259-1262
Reaction:
C2H5OC(O)N(CH3)2 → C2H4 + CO2 + (CH3)2NH
Reaction order:
1
Temperature:
588 - 653
K
Pressure: 4.00E-2 - 0.24 bar
Rate expression:
1.26x1012 [s-1] e-185413 [±1854 J/mole]/RT
Bath gas:
C2H5OC(O)N(CH3)2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 588 | 4.26E-5 |
| 600 | 9.10E-5 |
| 625 | 4.02E-4 |
| 650 | 1.59E-3 |
| 653 | 1.86E-3 |