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Title: Reaction of Acetyl Radicals with Buta-1,3-diene
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 69
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973ENC/LIS1505
Reaction:
1,3-Butadiene + CH3CO → Products
Reaction order:
2
Reference reaction:
CH3CO → CO + ·CH3
Reference reaction order:
1
Temperature:
333 - 397
K
Pressure: 0.27 bar
Rate expression:
2.49x10-24 [cm3/molecule] e43900 [±4390 J/mole]/RT
Uncertainty:
5.0
Bath gas:
C3H8
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule] |
|---|---|
| 333 | 1.92E-17 |
| 350 | 8.87E-18 |
| 375 | 3.24E-18 |
| 397 | 1.49E-18 |