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Title: Reactions of O(3P) Atoms with Unsaturated C3-Hydrocarbons
Volume: 1
Page(s):
Year: 1973
Book Title: Combust. Inst. European Symp.
Publisher address: ed. F. J. Weinberg, pub. Academic Press, London,
Reference type: Book Chapter
Squib: 1973HER13C
Reaction:
CH3CH=CH2 + O· → Methyloxirane
Reaction order:
2
Temperature:
275 - 360
K
Pressure: 6.67E-3 bar
Rate expression:
6.97x10-12 [cm3/molecule s] e-2104 [J/mole]/RT
Bath gas:
CH3CH=CH2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 275 | 2.78E-12 |
| 300 | 3.00E-12 |
| 325 | 3.20E-12 |
| 350 | 3.39E-12 |
| 360 | 3.45E-12 |