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Title: The kinetic deuterium isotope criterion applied to th thermolysis of alkyl allyl ethers. II
Journal: J. Am. Chem. Soc.
Volume: 95
Page(s): 5242 - 5245
Year: 1973
Reference type: Journal article
Squib: 1973KWA/SLU5242-5245
Reaction:
(CH3)2CHOCH2CH=CH2 → (CH3)2CO + CH3CH=CH2
Reaction order:
1
Reference reaction:
(CD3)2CDOCH2CH=CH2 → (CD3)2CO + CH2=CHCH2D
Reference reaction order:
1
Temperature:
710 - 797
K
Pressure: 1.01 bar
Rate expression:
6.0x10-1 e5438 [J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 710 | 1.51E0 |
| 725 | 1.48E0 |
| 750 | 1.44E0 |
| 775 | 1.40E0 |
| 797 | 1.36E0 |