Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Beadle, P.C.; Knox, J.H.
Title:   Activated chloroalkyl radicals in the chlorination of olefins
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   72
Page(s):   1418 - 1433
Year:   1974
Reference type:   Journal article
Squib:   1974BEA/KNO1418-1433

Reaction:   C2Cl5C2Cl4 + Cl
Reaction order:   1
Reference reaction:   C2Cl5 + Cl2CCl3CCl3 + Cl
Temperature:   300 - 350 K
Pressure:  0.27 bar
Rate expression:   2.95x1013 [s-1] e-64853 [±8314472 J/mole]/RT
Uncertainty:   3.1600001
Bath gas:   SF6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.51E2
325 1.11E3
350 6.18E3