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Accessibility information
Author(s):   Choo, K-Y.; Golden, D.M.; Benson, S.W.
Title:   Very Low-Pressure Pyrolysis (VLPP) of t-Butylmethyl Ether
Journal:   Int. J. Chem. Kinet.
Volume:   6
Page(s):  
Year:   1974
Reference type:   Journal article
Squib:   1974CHO/GOL631

Reaction:   tert-C4H9OCH3CH3OH + iso-C4H8
Reaction order:   1
Temperature:   888 - 1160 K
Rate expression:   7.94x1013 [s-1] e-246940 [±4939 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
888 2.37E-1
900 3.70E-1
925 9.02E-1
950 2.10E0
975 4.68E0
1000 1.00E1
1025 2.07E1
1050 4.13E1
1075 7.96E1
1100 1.49E2
1125 2.72E2
1150 4.83E2
1160 6.03E2