Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: No. 3. - Reactions des radicaux trichloromethyle avec des bromomethanes et deuteriobromomethanes. Effet isotopique primaire
Journal: J. Chim. Phys. Phys. Chim. Biol.
Volume: 71
Page(s):
Year: 1974
Reference type: Journal article
Squib: 1974HAU13
Reaction:
CH4 + ·CCl3 → CHCl3 + ·CH3
Reaction order:
2
Reference reaction:
CD4 + ·CCl3 → CCl3D + CD3
Reference reaction order:
2
Temperature:
488 - 573
K
Rate expression:
1.26x101 e-5853 [J/mole]/RT
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 488 | 2.98E0 |
| 500 | 3.08E0 |
| 525 | 3.30E0 |
| 550 | 3.50E0 |
| 573 | 3.69E0 |