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Accessibility information
Author(s):   Zabel, V.F.
Title:   Der thermische zerfall von chlorierten athylenen in der gasphase. I. Tetrachlorathylen und trichlorathylen
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   78
Page(s):  
Year:   1974
Reference type:   Journal article
Squib:   1974ZAB232

Reaction:   C2HCl3 → Products
Reaction order:   1
Temperature:   1450 - 1900 K
Pressure:  2.03 - 177 bar
Rate expression:   7.0x1015 [s-1] e-351702 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1450 1.50E3
1475 2.46E3
1500 3.96E3
1525 6.29E3
1550 9.84E3
1575 1.52E4
1600 2.31E4
1625 3.47E4
1650 5.14E4
1675 7.54E4
1700 1.09E5
1725 1.57E5
1750 2.23E5
1775 3.13E5
1800 4.36E5
1825 6.01E5
1850 8.22E5
1875 1.12E6
1900 1.50E6