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Accessibility information
Author(s):   Zabel, V.F.
Title:   Der thermische zerfall von chlorierten athylenen in der gasphase. I. Tetrachlorathylen und trichlorathylen
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   78
Page(s):  
Year:   1974
Reference type:   Journal article
Squib:   1974ZAB232

Reaction:   C2Cl4 → Products
Reaction order:   1
Temperature:   1450 - 1900 K
Pressure:  2.03 - 177 bar
Rate expression:   4.5x1014 [s-1] e-335073 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1450 3.83E2
1475 6.13E2
1500 9.66E2
1525 1.50E3
1550 2.30E3
1575 3.47E3
1600 5.18E3
1625 7.63E3
1650 1.11E4
1675 1.60E4
1700 2.28E4
1725 3.21E4
1750 4.49E4
1775 6.21E4
1800 8.51E4
1825 1.16E5
1850 1.56E5
1875 2.08E5
1900 2.76E5