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Accessibility information
Author(s):   Aders, W.-K.; Pangritz, D.; Wagner, H.Gg.
Title:   Untersuchungen zur reaktion von wasserstoffatomen mit methylfluoride, methylchlorid und methylbromid
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   79
Year:   1975
Reference type:   Journal article
Squib:   1975ADE/PAN90

Reaction:   CH3Br + ·CH3 + HBr
Reaction order:   2
Temperature:   298 - 652 K
Pressure:  2.13E-3 - 2.40E-2 bar
Rate expression:   2.16x10-11 [±4.98x10-12 cm3/molecule s] e-14966 [±1048 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Electron spin resonance (ESR or EPR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 5.14E-14
300 5.35E-14
325 8.49E-14
350 1.26E-13
375 1.78E-13
400 2.40E-13
425 3.12E-13
450 3.95E-13
475 4.88E-13
500 5.90E-13
525 7.00E-13
550 8.18E-13
575 9.43E-13
600 1.07E-12
625 1.21E-12
650 1.35E-12
652 1.37E-12