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Title: The nature of the transition state in ester pyrolysis. Part III. The Hammett correlation for pyrolysis of t-butyl benzoates
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s): 1802 - 1803
Year: 1975
Reference type: Journal article
Squib: 1975AMI/TAY1802-1803
Reaction:
Benzoic acid, 4-nitro-, 1,1-dimethylethyl ester → 4-Nitrobenzoic acid + iso-C4H8
Reaction order:
1
Reference reaction:
Benzoic acid 1,1-dimethylethyl ester → Benzoic acid + iso-C4H8
Reference reaction order:
1
Temperature:
585
K
Rate expression:
3.08
Bath gas:
Benzoic acid, 4-nitro-, 1,1-dimethylethyl ester
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Other (direct)
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