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Title: A kinetic study of the reaction of O(3P) with toluene
Journal: Int. J. Chem. Kinet.
Volume: 7
Page(s): 689 - 698
Year: 1975
Reference type: Journal article
Squib: 1975FUR/EBA689-698
Reaction:
Toluene + O· → Products
Reaction order:
2
Temperature:
373 - 648
K
Pressure: 1.33E-3 - 4.00E-3 bar
Rate expression:
8.7x10-12 [cm3/molecule s] e-11225 [±785 J/mole]/RT
Uncertainty:
1.3200001
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 373 | 2.33E-13 |
| 375 | 2.38E-13 |
| 400 | 2.98E-13 |
| 425 | 3.63E-13 |
| 450 | 4.33E-13 |
| 475 | 5.07E-13 |
| 500 | 5.85E-13 |
| 525 | 6.65E-13 |
| 550 | 7.47E-13 |
| 575 | 8.32E-13 |
| 600 | 9.17E-13 |
| 625 | 1.00E-12 |
| 648 | 1.08E-12 |