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Accessibility information
Author(s):   King, K.D.; Goddard, R.D.
Title:   Very Low-Pressure Pyrolysis of Cyclobutyl Cyanide. The Cyano Stabilization Energy
Journal:   Int. J. Chem. Kinet.
Volume:   7
Page(s):  
Year:   1975
Reference type:   Journal article
Squib:   1975KIN/GOD109

Reaction:   CyclobutanecarbonitrileC2H4 + CH2CHCN
Reaction order:   1
Temperature:   833 - 1200 K
Rate expression:   1.0x1015 [s-1] e-238625 [±4773 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
833 1.09E0
850 2.17E0
875 5.69E0
900 1.42E1
925 3.35E1
950 7.58E1
975 1.64E2
1000 3.43E2
1025 6.91E2
1050 1.35E3
1075 2.54E3
1100 4.67E3
1125 8.33E3
1150 1.45E4
1175 2.47E4
1200 4.10E4