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Accessibility information
Author(s):   Luu, S.H.; Glanzer, K.; Troe, J.
Title:   Thermal Isomerization in Shock Waves and Flash Photolysis of Cycloheptatriene, III
Journal:   Ber. Bunsenges. Phys. Chem.
Volume:   79
Page(s):  
Year:   1975
Reference type:   Journal article
Squib:   1975LUU/GLA855

Reaction:   1,3,5-CycloheptatrieneToluene
Reaction order:   1
Temperature:   600 - 1300 K
Pressure:  0.27 - 2.31 bar
Rate expression:   6.31x1013 [s-1] e-217839 [J/mole]/RT
Uncertainty:   1.12
Bath gas:   Ar
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
600 6.85E-6
650 1.97E-4
700 3.51E-3
750 4.25E-2
800 3.77E-1
850 2.59E0
900 1.44E1
950 6.65E1
1000 2.64E2
1050 9.19E2
1100 2.86E3
1150 8.05E3
1200 2.08E4
1250 4.98E4
1300 1.12E5