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Author(s):   Toby, F.S.; Toby, S.
Title:   The Reaction of Ozone with 1,3-Butadiene and with Allene
Journal:   Proc. Symp. Chem. Kinet. Data Upper Lower Atmos. 1974
Year:   1975
Reference type:   Journal article
Squib:   1975TOB/TOB197

Reaction:   1,3-Butadiene + O3 → Products
Reaction order:   2
Temperature:   273 - 343 K
Pressure:  1.33E-4 - 6.67E-3 bar
Rate expression:   1.05x10-13 [cm3/molecule s] e-24278 [±3401 J/mole]/RT
Uncertainty:   5.0
Bath gas:   1,3-Butadiene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 2.37E-18
275 2.56E-18
300 6.21E-18
325 1.31E-17
343 2.10E-17