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Title: The Kinetics of the Diels-Alder Addition of Cyclopentadiene to Acetylene and the Decomposition of Norbornadiene
Journal: Int. J. Chem. Kinet.
Volume: 7
Page(s):
Year: 1975
Reference type: Journal article
Squib: 1975WAL/WEL319
Reaction:
2,5-Norbornadiene → Toluene + 1,3,5-Cycloheptatriene
Reaction order:
1
Temperature:
584 - 630
K
Pressure: 0.13 bar
Rate expression:
7.94x1014 [s-1] e-214513 [±2145 J/mole]/RT
Uncertainty:
1.29
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 584 | 5.17E-5 |
| 600 | 1.68E-4 |
| 625 | 9.38E-4 |
| 630 | 1.30E-3 |