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Title: Reactivity of Primary and Secondary Carbon-Hydrogen Bonds in Radical Processes
Journal: React. Kinet. Catal. Lett.
Volume: 2
Page(s):
Year: 1975
Reference type: Journal article
Squib: 1975YAM449
Reaction:
n-C4H10 + ·CH3 → Other Products + CH4
Reaction order:
2
Reference reaction:
·CH3 + D2 → CH3D + D
Temperature:
980 - 1060
K
Pressure: 6.67E-2 bar
Rate expression:
5.25x10-12 [cm3/molecule s] e-46478 [±8398 J/mole]/RT
Uncertainty:
2.5699999
Bath gas:
n-C4H10
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 980 | 1.75E-14 |
| 1000 | 1.96E-14 |
| 1025 | 2.25E-14 |
| 1050 | 2.56E-14 |
| 1060 | 2.69E-14 |