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Title: Reactivity of Primary and Secondary Carbon-Hydrogen Bonds in Radical Processes
Journal: React. Kinet. Catal. Lett.
Volume: 2
Page(s):
Year: 1975
Reference type: Journal article
Squib: 1975YAM449
Reaction:
n-C4H10 + ·CH3 → CH4 + sec-C4H9
Reaction order:
2
Temperature:
980 - 1060
K
Pressure: 6.67E-2 bar
Rate expression:
7.09x10-13 [cm3/molecule s] e-43900 [J/mole]/RT
Bath gas:
n-C4H10
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 980 | 3.24E-15 |
| 1000 | 3.61E-15 |
| 1025 | 4.11E-15 |
| 1050 | 4.64E-15 |
| 1060 | 4.87E-15 |