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Title: Kinetics of the thermal unimolecular reactions of cyclohexene and 4-vinylcyclohexene behind reflected shock waves
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 72
Page(s):
Year: 1976
Reference type: Journal article
Squib: 1976BAR/PAR2404
Reaction:
4-Vinylcyclohexene → 1,3-Butadiene + 1,3-Butadiene
Reaction order:
1
Temperature:
927 - 1050
K
Pressure: 1.93 - 2.47 bar
Rate expression:
6.17x1015 [s-1] e-261906 [J/mole]/RT
Uncertainty:
1.55
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 927 | 1.08E1 |
| 950 | 2.45E1 |
| 975 | 5.74E1 |
| 1000 | 1.29E2 |
| 1025 | 2.78E2 |
| 1050 | 5.77E2 |