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Accessibility information
Author(s):   Bigley, D.B.; Weatherhead, R.H.
Title:   Studies in Decarboxylation. Part VIII. The Gas-phase Pyrolysis of βπ-Acetylenic Acids
Journal:   J. Chem. Soc. Perkin Trans. 2
Year:   1976
Reference type:   Journal article
Squib:   1976BIG/WEA592

Reaction order:   1
Temperature:   680 - 720 K
Pressure:  6.67E-2 - 0.67 bar
Rate expression:   2.34x1011 [s-1] e-172941 [±6918 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
680 1.22E-2
700 2.91E-2
720 6.65E-2