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Title: Studies in Decarboxylation. Part VIII. The Gas-phase Pyrolysis of βπ-Acetylenic Acids
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1976
Reference type: Journal article
Squib: 1976BIG/WEA592
Reaction:
CH3CH=CHCH2COOH → CH3CH=CHCH3 + CO2
Reaction order:
1
Temperature:
680 - 720
K
Pressure: 6.67E-2 - 0.67 bar
Rate expression:
2.34x1011 [s-1] e-172941 [±6918 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 680 | 1.22E-2 |
| 700 | 2.91E-2 |
| 720 | 6.65E-2 |