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Title: Studies in Decarboxylation. Part IX. The Gas-phase Pyrolysis of Some Acids containing Two Double Bonds
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1976
Reference type: Journal article
Squib: 1976BIG/WEA704
Reaction:
CH2=C=CHCH2COOH → 1,3-Butadiene + CO2
Reaction order:
1
Temperature:
665 - 715
K
Pressure: 6.67E-2 - 0.67 bar
Rate expression:
1.05x1011 [s-1] e-167952 [±6701 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 665 | 6.75E-3 |
| 675 | 1.06E-2 |
| 700 | 3.08E-2 |
| 715 | 5.64E-2 |