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Title: Reactions of chlorine atoms with ethane, propane, isobutane, fluoroethane, 1,1-difluoroethane, 1,1,1-trifluoroethane and cyclopropane
Journal: J. Chem. Soc. Chem. Commun.
Volume: 72
Page(s):
Year: 1976
Reference type: Journal article
Squib: 1976CAD/KIR1027
Reaction:
C2H5F + Cl → HCl + CH3C(·)HF
Reaction order:
2
Reference reaction:
CH3CHF2 + Cl → HCl + CH2CHF2
Reference reaction order:
2
Temperature:
283 - 367
K
Rate expression:
4.07 e4390 [±175 J/mole]/RT
Uncertainty:
1.0700001
Bath gas:
C2F6
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 283 | 2.63E1 |
| 300 | 2.37E1 |
| 325 | 2.07E1 |
| 350 | 1.84E1 |
| 367 | 1.72E1 |